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    2018-7-25 · A novel tetraoxolene-bridged Fe two-dimensional honeycomb layered compound, (NPr 4) 2 [Fe 2 (Cl 2 An) 3] ⋅2 (acetone)⋅H 2 O (1), where Cl 2 An n− =2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate and NPr 4 + =tetrapropylammonium cation, has been synthesized. 1 revealed a thermally induced valence tautomeric transition at T 1/2 =236 K (cooling)/237 K (heating) …Suzuki Coupling - Organic ChemistrySuzuki Coupling. The scheme above shows the first published Suzuki Coupling, which is the palladium-catalysed cross coupling between organoboronic acid and halides. Recent catalyst and methods developments have broadened the possible applications enormously, so that the scope of the reaction partners is not restricted to aryls, but includes ...

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